Saturday, January 31, 2009

The Most Advanced Quadruped Robot on Earth

Runs at 4 mph, climbs slopes up to 35 degrees, walks across rubble, and carries a 340 lb load.

BigDog is the alpha male of the Boston Dynamics family of robots. It is a quadruped robot that walks, runs, and climbs on rough terrain and carries heavy loads. BigDog is powered by a gasoline engine that drives a hydraulic actuation system. BigDog's legs are articulated like an animal’s, and have compliant elements that absorb shock and recycle energy from one step to the next. BigDog is the size of a large dog or small mule, measuring 1 meter long, 0.7 meters tall and 75 kg weight.

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BigDog has an on-board computer that controls locomotion, servos the legs and handles a wide variety of sensors. BigDog’s control system manages the dynamics of its behavior to keep it balanced, steer, navigate, and regulate energetics as conditions vary. Sensors for locomotion include joint position, joint force, ground contact, ground load, a laser gyroscope, and a stereo vision system. Other sensors focus on the internal state of BigDog, monitoring the hydraulic pressure, oil temperature, engine temperature, rpm, battery charge and others.

In separate trials, BigDog runs at 4 mph, climbs slopes up to 35 degrees, walks across rubble, and carries a 340 lb load.

BigDog is being developed by Boston Dynamics with the goal of creating robots that have rough-terrain mobility that can take them anywhere on Earth that people and animals can go. The program is funded by the Defense Advanced Research Project Agency (DARPA).

Watch a video: http://www.bostondynamics.com/content/sec.php?section=BigDog

Friday, January 30, 2009

New way to efficiently convert ethanol and other biofuels into hydrogenPermalink

Researchers here have found a way to convert ethanol and other biofuels into hydrogen very efficiently.

A new catalyst makes hydrogen from ethanol with 90 percent yield, at a workable temperature, and using inexpensive ingredients.

Umit Ozkan, professor of chemical and biomolecular engineering at Ohio State University, said that the new catalyst is much less expensive than others being developed around the world, because it does not contain precious metals, such as platinum or rhodium.

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"Rhodium is used most often for this kind of catalyst, and it costs around $9,000 an ounce," Ozkan said. "Our catalyst costs around $9 a kilogram."

She and her co-workers presented the research Wednesday, August 20 at the American Chemical Society meeting in Philadelphia.

The Ohio State catalyst could help make the use of hydrogen-powered cars more practical in the future, she said.

"There are many practical issues that need to be resolved before we can use hydrogen as fuel -- how to make it, how to transport it, how to create the infrastructure for people to fill their cars with it," Ozkan explained.

"Our research lends itself to what's called a 'distributed production' strategy. Instead of making hydrogen from biofuel at a centralized facility and transporting it to gas stations, we could use our catalyst inside reactors that are actually located at the gas stations. So we wouldn't have to transport or store the hydrogen -- we could store the biofuel, and make hydrogen on the spot."

The catalyst is inexpensive to make and to use compared to others under investigation worldwide. Those others are often made from precious metals, or only work at very high temperatures.

"Precious metals have high catalytic activity and -- in most cases -- high stability, but they're also very expensive. So our goal from the outset was to come up with a precious-metal-free catalyst, one that was based on metals that are readily available and inexpensive, but still highly active and stable. So that sets us apart from most of the other groups in the world."

The new dark gray powder is made from tiny granules of cerium oxide -- a common ingredient in ceramics -- and calcium, covered with even smaller particles of cobalt. It produces hydrogen with 90 percent efficiency at 660 degrees Fahrenheit (around 350 degrees Celsius) -- a low temperature by industrial standards.

"Whenever a process works at a lower temperature, that brings energy savings and cost savings," Ozkan said. “Also, if the catalyst is highly active and can achieve high hydrogen yields, we don’t need as much of it. That will bring down the size of the reactor, and its cost”.

The process starts with a liquid biofuel such as ethanol, which is heated and pumped into a reactor, where the catalyst spurs a series of chemical reactions that ultimately convert the liquid to a hydrogen-rich gas.

One of the biggest challenges the researchers faced was how to prevent "coking" -- the formation of carbon fragments on the surface of the catalyst. The combination of metals -- cerium oxide and calcium -- solved that problem, because it promoted the movement of oxygen ions inside the catalyst. When exposed to enough oxygen, the carbon, like the biofuel, is converted into a gas and gets oxidized; it becomes carbon dioxide.

At the end of the process, waste gases such as carbon monoxide, carbon dioxide and methane are removed, and the hydrogen is purified. To make the process more energy-efficient, heat exchangers capture waste heat and put that energy back into the reactor. Methane recovered in the process can be used to supply part of the energy.

Though this work was based on converting ethanol, Ozkan's team is now studying how to use the same catalyst with other liquid biofuels. Her coauthors on this presentation included Ohio State doctoral students Hua Song and Lingzhi Zhang.

Source: Ohio State University

Thursday, January 29, 2009

Ferroelectric polymer-based capacitors can deliver power more rapidly and are much lighter than conventional batteries

The proliferation of solar, wind and even tidal electric generation and the rapid emergence of hybrid electric automobiles demands flexible and reliable methods of high-capacity electrical storage. Now a team of Penn State materials scientists is developing ferroelectric polymer-based capacitors that can deliver power more rapidly and are much lighter than conventional batteries.

"Electrical energy storage is very important for all electrical and electronic systems," says Qing Wang, associate professor of materials science and engineering. "Even renewable energy systems like solar cells need somewhere to store excess energy to be used at night."

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Wang and his research team report today (Aug. 20) at the 236th national American Chemical Society meeting in Philadelphia in two papers, on the development of power density tunable polymers and polymer ceramic nanocomposites as electric storage materials for capacitors. Currently, power conditioning is carried out by capacitors, but Wang believes that eventually properly tuned polymer capacitors could replace batteries.

"Traditional materials are ceramic materials which have high weight and are very fragile," says Wang. "Mobile electronics need light weight electrical energy storage."

The researchers, who include Wang, Yingying Lu, postdoctoral fellow, and Jason Claude, Junjun Li, graduate students in materials science and engineering, developed a polymer of poly(vinylidene fluoride) and trifluoroethylene which, with the addition of chlorotrifluoroethylene had a very high dielectric permittivity at room temperature. Permittivity is a measure of how much charge is stored in a material for a given electric field and is an indicator of how effective a material will be when storing energy in a capacitor. They found that by altering the amounts of the various chemical components of the polymer, they could tune the dielectric property and energy density.

Hybrid cars are a good target for ferroelectric polymer capacitors because they convert mechanical energy generated when, for example coasting downhill, convert it to electricity and charge batteries for use at other times. Conventional batteries are often heavy, and may not be able to deliver the power amounts needed for quick acceleration.

Wang and Li, report on a further modification of this ferroelectric polymer by adding nanoparticulate ceramics to further improve the energy density. Because ceramics often have higher permittivities than the polymers, they believed that combining polymers with high breakdown strength with ceramics of high permittivity would produce a composite material with a large energy storage capacity. Breakdown strength is a measure of the maximum electric field that an insulating material can withstand before it begins to conduct electricity. The higher the breakdown strength, the better a material is for a capacitor.

Unfortunately mixing nano particles of ceramic with polymers is not a simple action. The ceramic particles tend to clump and aggregate. If the two materials are not matched for electrical properties, their interface will breakdown at high electric fields and the ability of the composite to store energy will decrease, rather than increase. Wang and his team fine-tuned the dielectric particles to the polymer matrix by adding functionalized groups to the materials to match them. They also tried to control the mixing so that uniformly dispersed particles are spread through the matrix.

"Matching the permittivity and uniformly dispersing the ceramic nanoparticles is not easy," says Wang. "Both problems have to be tackled and solved at the same time for the material to have the desired characteristics."

Dielectric polymers like the ones Wang creates cannot only be used as capacitors, but could also substitute for the dielectric silicon dioxide layer currently used in computers. Because polymers are processed at room temperature, they are easily fabricated and they are extremely flexible. Their use would open the way for flexible electronics applications, such as foldable screens and computers.

Source: Penn State

Wednesday, January 28, 2009

Microorganisms that convert hydrocarbons to natural gas isolated

When a group of University of Oklahoma researchers began studying the environmental fate of spilt petroleum, a problem that has plagued the energy industry for decades, they did not expect to eventually isolate a community of microorganisms capable of converting hydrocarbons into natural gas.

The researchers found that the groundbreaking process—known as anaerobic hydrocarbon metabolism—can be used to stimulate methane gas production from older, more mature oil reservoirs like those in Oklahoma. The work has now led to the recognition that similar microorganisms may also be involved in problems ranging from the deterioration of fuels to the corrosion of pipelines.

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A new OU initiative led by Joseph Suflita, Director of the Institute for Energy and Environment within the Mewbourne College of Earth and Energy, brings together researchers from multiple disciplines and departments to attack the corrosion problems affecting pipelines, storage tanks and tankers as well as the deterioration of fuels inside such facilities. Suflita says, “The OU initiative is the only major U.S. initiative of its kind devoted to the problem of biodeterioration and biocorrosion.”

Biodeterioration and biocorrosion are fundamental microbiological processes that can cause pipelines, storage facilities and tankers to leak and contaminate the environment. “First, we have to understand how Mother Nature cleans up these spills and we can do this by studying the way microorganisms interact with hydrocarbons,” says Suflita. OU researchers have isolated some interesting organisms that metabolize hydrocarbons in the absence of oxygen—insight that was lacking for a long time.

OU researchers have extended their studies to how energy is produced in this country by investigating biocorrosion that leads to pipeline failures on the North Slope of Alaska. “We want to better understand how organisms eat through these pipelines. Several fundamental mechanisms cause this problem, but it is spotty and doesn’t occur all of a sudden. Rather, biocorrosion occurs over a long period of time, and we are using a series of new molecular and chemical tools to find out why and how this happens,” says Suflita.

“We think cells grow in communities that adhere to the inner surface of pipelines and form three-dimensional biofilms that can sometimes cause pitting. Once we understand what these microorganisms are doing, we can interrupt their processes or diagnose them more effectively. The science is rudimentary at this stage. The modern tools of molecular microbiology have not been applied yet, but a National Science Foundation grant, support from the DOE’s Joint Genome Institute and the cooperation of the energy industry, allowed us to study pipeline biocorrosion on the North Slope.”

Interruptions in energy supply are significant and cause price spikes that have global impact. Over 500,000 miles of pipeline that crisscross the United States carry over 75 percent of crude oil and 65 percent of refined product. Problems occur throughout the industry, in storage facilities, refineries and tankers, and have similar consequences. Microorganisms grow inside the pipelines because water often accompanies hydrocarbons pumped from the ground. As reservoirs age, more water is pumped creating an even greater problem.

“For many years, no one ever thought anaerobes could grow by metabolizing hydrocarbons in the absence of oxygen, but that is simply wrong. The organisms are actually quite good at it. The underlying mechanisms will be even more important as we introduce newer biofuels to augment our fossil fuel supply. We are putting new fuel combinations into the existing pipelines that service the entire country. The new biofuels can be less stable, so there is a different problem to deal with. The chemistry of biofuels may not allow us to store them as long and more research is needed to determine the stability, compatability and composition of such fuel mixtures.”

While biocorrosion and biodeterioration can be problematic, anaerobic hydrocarbon metabolism also has an upside. The OU researchers found that they can use their organisms to convert hydrocarbons in oil reservoirs to natural gas. “Because two-thirds of U.S. oil is still in place, we can use these organisms to convert residual hydrocarbons into natural gas and create a new source of domestic energy. The concept of anaerobic metabolism is an innovative process and the OU initiative is the only one of its kind in the United States at the present time. We are also experimenting with shales and other unconventional reservoirs.”

“Biotechnology can influence recovery and address some of today’s problems if we can understand how microorganisms degrade hydrocarbons in the absence of oxygen. OU is one of the top universities in the world to study anaerobic microbiology with 14 experts performing research in some aspect of this field. It is rare for universities to have even a single individual with this specialization. OU is an exciting place to be if you are an environmental microbiologist. This initiative has unified this group of experts and led to the groundbreaking research we have just begun to understand.”

“We know that bacterial cells communicate much like those that cause disease. If we know the language they use, we can send signals and interrupt their communications so they will change their behavior. The best way to treat the biocorrosion problem has not yet been determined. Active ongoing monitoring of pipelines tells us there is an ongoing process, but we need to get to the problem before it gets to the critical stage. Some and perhaps most microorganisms are not routinely monitored, so we have to understand the role they play in this process—information we can use to more effectively diagnose and treat the consequences.”

Source: University of Oklahoma

Tuesday, January 27, 2009

New way to fine-tune the light coming from quantum dots by manipulating them with pairs of lasers

Researchers from the National Institute of Standards and Technology (NIST) and the Joint Quantum Institute (JQI), a collaborative center of the University of Maryland and NIST, have reported a new way to fine-tune the light coming from quantum dots by manipulating them with pairs of lasers. Their technique, published in Physical Review Letters,* could significantly improve quantum dots as a source of pairs of “entangled” photons, a property with important applications in quantum information technologies. The accomplishment could accelerate development of powerful advanced cryptography applications, projected to be a key 21st-century technology.

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Entangled photons are a peculiar consequence of quantum mechanics. Tricky to generate, they remain interconnected even when separated by large distances. Merely observing one instantaneously affects the properties of the other. The entanglement can be used in quantum communication to pass an encryption key that is by its nature completely secure, as any attempt to eavesdrop or intercept the key would be instantly detected. One goal of the NIST-JQI team is to develop quantum dots as a convenient source of entangled photons.

Quantum dots are nanoscale regions of a semiconductor material similar to the material in computer processors but with special properties due to their tiny dimensions. Though they can be composed of tens of thousands of atoms, quantum dots in many ways behave almost as if they were single atoms. Unfortunately, almost is not good enough when it comes to the fragile world of quantum cryptography and next-generation information technologies. When energized, a quantum dot emits photons, or “particles” of light, just as a solitary atom does. But imperfections in the shape of a quantum dot cause what should be overlapping energy levels to separate. This ruins the delicate balance of the ideal state required to emit entangled photons.

To overcome this problem, the NIST-JQI team uses lasers to precisely control the energy levels of quantum dots, just as physicists have been doing with actual single atoms since the mid-1970s and, much more recently, with the artificial quantum dot variety. With their customized set-up, which includes two lasers—one shining from above the quantum dot and the other illuminating it from the side—the researchers were able to manipulate energy states in a quantum dot and directly measure its emissions. By adjusting the intensity of the laser beams, they were able to correct for imperfection-caused variations and generate more ideal signals. In so doing, the team was the first to demonstrate that laser-tuned quantum dots can efficiently generate photons one at a time, as required for quantum cryptography and other applications.

While the device currently still requires quite cold temperatures and sits in a liquid helium bath, it is compact enough to fit in the palm of your hand—an elegant setup that could be eventually implemented in quantum cryptography applications.

Source: NIST

Monday, January 26, 2009

Can biofuels be sustainable?

With oil prices skyrocketing, the search is on for efficient and sustainable biofuels. Research published this month in Agronomy Journal examines one biofuel crop contender: corn stover.

Corn stover is made up of the leaves and stalks of corn plants that are left in the field after harvesting the edible corn grain. Corn stover could supply as much as 25% of the biofuel crop needed by 2030.

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Scientists with the USDA-ARS Agroecosystem Unit located at the University of Nebraska examined the long-term sustainability of using corn stover as a biofuel crop.

When corn stover is not harvested as a biofuel crop, it can be left on the fields to restore vital nutrients to the soil. Full-scale harvesting of corn stover may deplete the soil.

Researchers measured the soil organic carbon levels and residue production over 14 years in fields planted continuously with corn, continuously with soybeans, and with a rotation of corn and soybeans. Organic carbon rates were found to stay steady or even increase in all three field types.

Gary Varvel and Wally Wilhelm, who conducted the study, said "These results suggest that a portion of corn stover could be harvested for biofuel production without reducing soil organic carbon levels in high yielding systems. However, since this study did not study the direct impact of stover removal, that aspect remains to be evaluated."

Research into the effects of residue removal on soil organic carbon levels in several different cropping systems is ongoing at this and several other USDA-ARS locations throughout the U.S. Much of this research is under the auspices of a multi-location CRIS project within ARS called REAP (Renewable Energy Assessment Project).

Full Article: http://agron.scijournals.org/cgi/content/abstract/100/4/1180

Source: American Society of Agronomy

Sunday, January 25, 2009

Optical computing closer to reality

Scientists at the University of Pennsylvania have theorized a way to increase the speed of pulses of light that bound across chains of tiny metal particles to well past the speed of light by altering the particle shape. Application of this theory would use nanosized metal chains as building blocks for novel optoelectronic and optical devices, which would operate at higher frequencies than conventional electronic circuits. Such devices could eventually find applications in the developing area of high-speed optical computing, in which protons and light replace electrons and transistors for greater performance.

Colleagues in the Department of Bioengineering, Alexander A. Govyadinov and Vadim A. Markel, also of the Department of Radiology at Penn, published the study in a recent issue of the journal Physical Review B.

Recent developments in nanotechnology have enabled researchers to fabricate nanoparticle chains with great precision and fidelity. Penn’s research team took advantage of this technological advance by utilizing metallic nanoparticles as a chain of miniature waveguides that exchange light.

Currently, the advance is theoretical. But, from a practical standpoint, the creation of a metallic nanochain would provide the combination of smaller-diameter optical components coupled with larger bandwidth, making them optimal wave guiding materials. As the velocity of the light pulse increases, so too does the operating bandwidth of a waveguide. Increasing the bandwidth helps to increase the number of information channels, allowing more information to flow simultaneously through a waveguide.

Researchers investigated changing the shape of particles in an attempt to increase this bandwidth. Spherically-shaped nanoparticles, the shape used almost exclusively in early research, provide narrow bandwidths of light. As Markel and Govyadinov discovered, shaping the particles as prolate, cigar-shaped or oblate, saucer-shaped, spheroids boosted the velocities of surface plasmon pulses reflecting off the surface to 2.5 times the speed of light in a vacuum.

Reshaping the nanoparticles therefore resulted in an enormous increase in the operating bandwidth of the waveguide. As an additional bonus, constructing the chains from oblate spheroids results in decreased power loss as well.
The exceptional combination of small size, large bandwidth and relatively small losses may make these useful as building blocks for the light-based devices of the future.

Researchers have used light and metal to create special electromagnetic wave of electrons on the surface called plasmons for years. Just as light travels through optical fibers, surface plasmons propagate along a chain of closely spaced, metallic particles with each particle acting like a miniature beacon, receiving a signal from its neighbor and transmitting it further along the chain. Although chains of metallic particles are not practical for long-range communication due to rapid power loss, they are well suited for optoelectronic and optical devices in which achieving a small overall size is important.

Markel and Govyadinov’s theory may prove useful in overcoming sizing obstacles that complicate optics. Light cannot travel through an optical fiber if the fiber’s diameter is smaller than a micron. A particle chain like the one proposed by Penn researchers, however, could be as thin as 50 nanometers in diameter, a few hundred times thinner than any optical fiber, and still guide the surface plasmon waves.

An interesting conundrum arises from the work. The theory of relativity prohibits anything from moving faster than light.
“But what is a ‘thing’?” Markel said. “A very powerful flashlight directed at the moon would theoretically create a bright spot on its surface. By simply turning the flashlight sideways, the flashlight’s beam streaks across the sky at speeds far exceeding the speed of light. This evidence has long been known and dismissed, since the bright spot cannot be used for superluminal, or faster-than-light communication, between the earth and the moon. The fast motion of the bright spot is simply a geometrical artifact, similar, in some ways, to the point at which the two blades of closing scissors intersect. The theory of relativity does not concern such purely geometrical objects.”

The researchers believe there are, in fact, some superluminal "things" in nature. For example, it has been long theorized, and was demonstrated in a series of experiments in the last quarter of the 20th century, that electromagnetic pulses, or "wave packets," can propagate through material media with an overall velocity which is greater that the speed of light in vacuum. Although the superluminal wave packets cannot be used to transmit energy or information faster than the speed of light, and therefore do not contradict the theory of relativity, they are fascinating objects and can be utilized in optical communications.

The surface plasmon pulses discovered at Penn belong to the same class of superluminal wave packets. It is predicted that the superluminal properties of these pulses are much bolder than anything previously observed.

Source: University of Pennsylvania

Saturday, January 24, 2009

The next ‘American Idol’? Ask your computer

New software shows promise in predicting breakout artists
Could a computer pick the next “American Idol”? The next Ludacris or Madonna?

New software by Israeli researchers promises to take much of the guesswork (and endless cover songs) out of figuring out which hip-hop or R & B artist will be the next "it" star in the United States. Using a mathematical formula to sort music requests logged by the massive Gnutella peer-to-peer file-sharing network, the researchers have boasted an enviable 15 percent to 30 percent success rate in automatically choosing artists or bands with breakout potential.

The solution, according to Tel Aviv University electrical engineer Yuval Shavitt and his colleagues, “is based on the observation that emerging artists, especially rappers, have a discernable stronghold of fans in their hometown area, where they are able to perform and market their music.”

Crucially, the researchers were able to extract geographic information from many of the 10 million to 40 million requests logged by Gnutella users every day. In some cases, the locations could be pinpointed to the level of a city borough, as in New York.

“What’s happening on the Internet is that it’s a whole collection of individual actions,” Shavitt said. “Such a huge collection of actions should have a very strong signal about many things, and in this case, it was so obvious that it should be a way to pick up trends — music, for example.”